|
MANUFACTURER'S NAME:
|
NATIONAL COATINGS CORPORATION
1201 CALLE SUERTE
CAMARILLO, CA 93012
www.nationalcoatings.com
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|
EMERGENCY TELEPHONE:
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800-423-9557
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DATE OF LAST REVISION:
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07/14/99
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SECTION 1 - CHEMICAL PRODUCT / COMPANY INFORMATION
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Product Name:
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RustShield Low VOC
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Revision
Date:
|
5/20/2008
|
|
Identification
Number:
|
A120
|
Supersedes :
|
N/A
|
|
Product
Use/Class:
|
Waterborne Acrylic - FOR
INDUSTRIAL USE ONLY
|
|
|
|
Supplier:
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National Coatings Corporation
1201 Calle Suerte
Camarillo, CA 93012
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|
|
SECTION II - HAZARDOUS INGREDIENTS / EXPOSURE LIMITS
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Chemical Name
|
CAS Number
|
Weight % Less Than
|
ACGIH TLV-TWA
|
ACGIH TLV-STEL
|
OSHA PEL-TWA
|
OSHA-CEIL
|
|
ZINC PHOSPHATE
|
7779-90-0
|
15.0
|
10 MG/M3
|
10 MG/M3
|
N/E
|
N/E
|
|
CALCIUM CARBONATE
|
1317-65-3
|
10.0
|
3 MGM3
|
N/E
|
5 MGM3
|
NE
|
|
DM GLYCOL ETHER
|
111-77-3
|
5.0
|
NE
|
NE
|
NE
|
NE
|
|
GLYCOL ETHER SOLVENT
|
112-34-5
|
5.0
|
NE
|
N/E
|
NE
|
NE
|
|
DIBUTYL PHTHALATE
|
84-74-2
|
5.0
|
5 MGM3
|
N/E
|
5 MGM3
|
NE
|
|
CARBON BLACK
|
1333-86-4
|
0.2
|
N/E
|
N/E
|
N/E
|
N/E
|
SECTION 3 - HAZARDS IDENTIFICATION
Emergency Overview: Use ventilation necessary to keep exposures below recommended exposure limits, if any.
Effects of Overexposure - Eye Contact: May cause eye irritation.
Effects of Overexposure - Skin Contact: May cause skin irritation.
Effects of Overexposure - Inhalation: Harmful if inhaled, may affect the brain or nervous system, causing dizziness, headache, or nausea. May cause nose and throat irritation. Use in inadequately ventilated areas may result in irritation headache and nausea.
Effects of Overexposure - Ingestion: May be harmful if swallowed.
Effects of Overexposure - Chronic Hazards: Under normal use conditions, this product is not expected to cause adverse health effects. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage.
Primary Route(s) of Entry: Skin Contact, Skin Absorption, Inhalation, Ingestion, Eye Contact
Medical Conditions Prone to Aggravation by Exposure: If you have a condition that could be aggravated by exposure to dust or organic vapors, see a physician prior to use.
SECTION 4 - FIRST AID MEASURES
First Aid - Eye Contact: If material gets into eyes, flush with water immediately for 15 minutes. Consult a physician.
First Aid - Skin Contact: Launder clothing before reuse. In case of contact, wash skin immediately with soap and water.
First Aid - Inhalation: If inhaled, remove to fresh air. Administer oxygen if necessary. Consult a physician if symptoms persist or exposure was severe.
First Aid - Ingestion: If swallowed do not induce vomiting. Seek immediate medical attention.
SECTION 5 - FIRE FIGHTING MEASURES
|
Flash Point, F: 201F (94C)
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Lower Explosive Limit, %: 0.6
|
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(Setaflash)
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Upper Explosive Limit, %: 24.6
|
Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog
Unusual Fire and Explosion Hazards: None known.
Special Firefighting Procedures: Non-flammable. Cool fire-exposed containers using water spray.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Steps to Be Taken If Material Is Released or Spilled: If a spill or leak occurs, contain the material. It can be allowed to dry or cure and presents no health or fire hazard. The material can then be removed and disposed of as non-hazardous waste. Before drying, the material can be washed or removed using soap and water.
SECTION 7 - HANDLING AND STORAGE
Handling: Avoid breathing vapors or spray mist. Do not get in eyes, on skin, or on clothing. Keep container tightly closed when not in use. Wear personal protection equipment. Do not breathe vapors. Wash thoroughly after handling. If pouring or transferring materials, ground all containers and tools. Do not weld, heat, cut or drill on full or empty containers. Use only in accordance with National Coatings Corporation application instructions, container label and Product Data Sheet.
Storage: Protect from Freezing! Keep container closed when not in use.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering Controls: Use explosion-proof ventilation when required to keep below health exposure guidelines and Lower Explosion Limit (LEL).
Respiratory Protection: Use only with ventilation to keep levels below exposure guidelines listed in Section 2. User should test and monitor exposure levels to ensure all personnel are below guidelines. If not sure, or not able to monitor, use MSHA/NIOSH approved supplied air respirator. Follow all current OSHA requirements for respirator use. For silica containing coatings in a liquid state, and/or if no exposure limits are established in Section 2 above, supplied air respirators are generally not required.
Skin Protection: Recommend impervious gloves and clothing to avoid skin contact. If material penetrates to skin, change gloves and clothing. The use of protective creams may be beneficial to certain individuals. Protective creams should be applied before exposure.
Eye Protection: Recommend safety glasses with side shields or chemical goggles to avoid eye contact.
Other protective equipment: Eye wash and safety showers should be readily available.
Hygienic Practices: Wash with soap and water before eating, drinking, smoking, applying cosmetics, or using toilet facilities. Use of a hand cleaner is recommended. Launder contaminated clothing before reuse. Leather shoes can absorb and allow hazardous materials to pass through. Check shoes carefully after soaking before reuse. Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate work area should be prohibited.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
|
Boiling Range:
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212 F (100 C) - 644 F (340 C)
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Vapor Density:
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Heavier than Air
|
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Odor:
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Ammoniacal
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Odor Threshold:
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N/D
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Appearance:
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Viscous Liquid, Various Colors
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Evaporation Rate:
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Slower Than Ether
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Solubility in H2O:
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N/D
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|
|
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Freeze Point:
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N/D
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Specific Gravity:
|
app. 1.22
|
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Vapor Pressure:
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N/D
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PH:
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N/D
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Physical State:
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Liquid
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|
|
(See section 16 for abbreviation legend)
SECTION 10 - STABILITY AND REACTIVITY
Conditions to Avoid: None
Incompatibility: Avoid contact with strong oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide, nitrogen oxides, and unidentified organic compounds. Consider all smoke and fumes from burning material as very hazardous. Welding, cutting or abrasive grinding can create smoke and fumes. Do not breathe any fumes or smoke from these operations.
Hazardous Polymerization: Will not occur under normal conditions.
Stability: This product is stable under normal storage conditions.
SECTION 11 - TOXICOLOGICAL INFORMATION
|
Product LD50: N/D
|
Product LC50: N/D
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|
Chemical Name
|
CAS Number
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LD50
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ACGIH TLV-TWA
|
|
ZINC PHOSPHATE
|
7779-90-0
|
> 552 MG/KG, ORAL RAT
|
10 MG/M3
|
|
CALCIUM
CARBONATE
|
1317-65-3
|
NOT AVAILABLE
|
3 MGM3
|
|
DM GLYCOL ETHER
|
111-77-3
|
>7000 MG/KG, ORAL, RAT
|
NE
|
|
GLYCOL ETHER SOLVENT
|
112-34-5
|
7292MG/KG,ORAL,RAT 2406MG/KG,ORAL MOUSE
|
NE
|
|
DIBUTYL PHTHALATE
|
84-74-2
|
20,000 MG/KG, ORAL, RAT
|
5 MGM3
|
|
CARBON BLACK
|
1333-86-4
|
NOT AVAILABLE
|
N/E
|
SECTION 12 - ECOLOGICAL INFORMATION
Ecological Information: No data
SECTION 13 - DISPOSAL INFORMATION
Disposal Information: Dispose of in accordance with State, Local, and Federal Environmental regulations.
Responsibility for proper waste disposal is with the owner of the waste.
SECTION 14 - TRANSPORTATION INFORMATION
|
DOT Proper Shipping Name:
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Not Regulated
|
Packing Group:
|
N/A
|
|
DOT Technical Name:
|
N/A
|
Hazard Subclass:
|
N/A
|
|
DOT Hazard Class:
|
None
|
Resp. Guide Page:
|
N/A
|
|
DOT UN/NA Number:
|
N/A
|
|
|
|
Additional Notes:
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None
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|
|
SECTION 15 - REGULATORY INFORMATION
CERCLA - SARA HAZARD CATEGORY
This product has been reviewed according to the EPA Hazard Categories promulgated under Sections 311and
312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
SARA SECTION 313
This product contains the following substances subject to the reporting requirements of Section 313 of Title III
of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
|
Chemical Name
|
CAS Number
|
|
ZINC PHOSPHATE
|
7779-90-0
|
|
GLYCOL ETHER SOLVENT
|
112-34-5
|
|
DIBUTYL PHTHALATE
|
84-74-2
|
TOXIC SUBSTANCES CONTROL ACT
All components of this product are listed on the TSCA inventory.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if
exported from the United States:
No TSCA 12(B) Substances exist in this product
U.S. STATE REGULATIONS AS FOLLOWS:
NEW JERSEY RIGHT-TO-KNOW
The following materials are non-hazardous, but are among the top five components in this product.
|
Chemical Name
|
CAS Number
|
|
WATER
|
7732-18-5
|
|
ACRYLIC RESIN
|
CTS-601
|
|
TITANIUM DIOXIDE
|
13463-67-7
|
PENNSYLVANIA RIGHT-TO-KNOW
The following non-hazardous ingredients are present in the product at greater than 3%.
|
Chemical Name
|
CAS Number
|
|
WATER
|
7732-18-5
|
|
ACRYLIC RESIN
|
CTS-601
|
|
TITANIUM DIOXIDE
|
13463-67-7
|
|
IRON OXIDE
|
1332-37-2
|
CALIFORNIA PROPOSITION 65
Warning: The following ingredients present in the product are known to the state of California to cause
Cancer:
|
Chemical Name
|
CAS Number
|
|
CARBON BLACK
|
1333-86-4
|
|
MICROCRYSTALLINE SILICA
|
14808-60-7
|
Warning: The following ingredients present in the product are known to the state of California to cause
birth defects, or other reproductive hazards:
|
Chemical Name
|
CAS Number
|
|
DIBUTYL PHTHALATE
|
84-74-2
|
INTERNATIONAL REGULATIONS AS FOLLOWS:
CANADIAN WHMIS
This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16
headings.
CANADIAN WHMIS CLASS: D2A, D2B
SECTION 16 - OTHER INFORMATION
HMIS Ratings
| Health: 1 |
Flammability: 1
|
Reactivity: 0
|
Personal Protection: X
|
VOLATILE ORGANIC COMPOUNDS, GR/LTR MIXED (UNTHINNED): 100
REASON FOR REVISION: N/A
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
The information contained herein is, to the best of our knowledge and belief accurate. However, since the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by use of this material. It is the responsibility of the user to comply with all applicable federal, state, and local laws and regulations.